From: Subject: CALCIUM ACETATE Date: Mon, 8 Dec 2008 15:03:10 -0500 MIME-Version: 1.0 Content-Type: multipart/related; type="text/html"; boundary="----=_NextPart_000_0070_01C95946.15EB1340" X-MimeOLE: Produced By Microsoft MimeOLE V6.00.2900.5579 This is a multi-part message in MIME format. ------=_NextPart_000_0070_01C95946.15EB1340 Content-Type: text/html; charset="Windows-1252" Content-Transfer-Encoding: quoted-printable Content-Location: http://www.jtbaker.com/msds/englishhtml/C0266.htm CALCIUM ACETATE

MSDS Number: C0266 * * * * * Effective Date: 11/09/06 * = * * * *=20 Supercedes: 03/30/04

CALCIUM ACETATE

1. Product Identification

Synonyms: Calcium diacetate; acetic acid, calcium = salt.=20
CAS No.: 62-54-4
Molecular Weight: 158.17=20
Chemical Formula: (CH3COO)2Ca
Product Codes: = 1265, 1658,=20 1660, 2003, 2156, 3754, 4047, 4048, 4210, 4573

2. Composition/Information on Ingredients

  Ingredient  =
                              CAS No         Percent        Hazardous    =
                             =20
  ---------------------------------------   ------------   ------------  =
 ---------  =20
=20
  Calcium Acetate                           62-54-4          99 - 100%   =
    No                                                                   =
 =20
=20

3. Hazards Identification

Emergency Overview
-------------------------- =
As=20 part of good industrial and personal hygiene and safety procedure, = avoid all=20 unnecessary exposure to the chemical substance and ensure prompt = removal from=20 skin, eyes and clothing.

SAF-T-DATA^(tm) = Ratings=20 (Provided here for your convenience)=20 =
---------------------------------------------------------------------= --------------------------------------=20
Health Rating: 0 - None
Flammability Rating: 1 - Slight =
Reactivity=20 Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective = Equip:=20 GOGGLES; LAB COAT; PROPER GLOVES
Storage Color Code: Green = (General=20 Storage)=20 =
---------------------------------------------------------------------= --------------------------------------=20

Potential Health Effects =
----------------------------------=20

Inhalation:
Not expected to be a health hazard.=20
Ingestion:
Not expected to be a health hazard. =
Skin=20 Contact:
Not expected to be a health hazard from skin = exposure.=20
Eye Contact:
No adverse effects expected. =
Chronic=20 Exposure:
No information found.
Aggravation of = Pre-existing=20 Conditions:
No information found.

4. First Aid Measures

Inhalation:
Remove to fresh air. Get medical = attention=20 for any breathing difficulty.
Ingestion:
Give several = glasses=20 of water to drink to dilute. If large amounts were swallowed, get = medical=20 advice.
Skin Contact:
Wash exposed area with soap and = water.=20 Get medical advice if irritation develops.
Eye Contact: =
Wash=20 thoroughly with running water. Get medical advice if irritation = develops.=20

5. Fire Fighting Measures

Fire:
When heated above 160C (320F) in enclosed = spaces=20 may generate highly flammable/explosive acetone.
Explosion: =
Not=20 considered to be an explosion hazard, except when heated (See above).=20
Fire Extinguishing Media:
Use any means suitable for=20 extinguishing surrounding fire.
Special Information:
In = the=20 event of a fire, wear full protective clothing and NIOSH-approved=20 self-contained breathing apparatus with full facepiece operated in the = pressure demand or other positive pressure mode. Water spray may be = used to=20 keep fire exposed containers cool.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal=20 protective equipment as specified in Section 8. Spills: Sweep up and=20 containerize for reclamation or disposal. Vacuuming or wet sweeping = may be=20 used to avoid dust dispersal.

7. Handling and Storage

Containers of this material may be hazardous when empty = since they=20 retain product residues (dust, solids); observe all warnings and = precautions=20 listed for the product. Keep in a tightly closed container, stored in = a cool,=20 dry, ventilated area. Protect against physical damage.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.=20
Ventilation System:
A system of local and/or general = exhaust is=20 recommended to keep employee exposures as low as possible. Local = exhaust=20 ventilation is generally preferred because it can control the = emissions of the=20 contaminant at its source, preventing dispersion of it into the = general work=20 area. Please refer to the ACGIH document, Industrial Ventilation, A = Manual=20 of Recommended Practices, most recent edition, for details.=20
Personal Respirators (NIOSH Approved):
For conditions = of use=20 where exposure to dust or mist is apparent and engineering controls = are not=20 feasible, a particulate respirator (NIOSH type N95 or better filters) = may be=20 worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, = etc.) are=20 present, use a NIOSH type R or P filter. For emergencies or instances = where=20 the exposure levels are not known, use a full-face positive-pressure,=20 air-supplied respirator. WARNING: Air-purifying respirators do not = protect=20 workers in oxygen-deficient atmospheres.
Skin Protection: =
Wear=20 protective gloves and clean body-covering clothing.
Eye = Protection:=20
Use chemical safety goggles. Maintain eye wash fountain and = quick-drench=20 facilities in work area.

9. Physical and Chemical Properties

Appearance:
Coarse, white powder. =
Odor:=20
Slight acetic acid odor.
Solubility:
Soluble in = water.=20
Density:
ca. 1.5
pH:
7.6 (0.2M aq. sol.) =
% Volatiles by volume @ 21C (70F):
0
Boiling = Point:=20
No information found.
Melting Point:
> 160C = (> 320F)=20 Decomposes to form acetone, calcium carbonate.
Vapor Density=20 (Air=3D1):
No information found.
Vapor Pressure (mm = Hg):=20
No information found.
Evaporation Rate (BuAc=3D1): =
No=20 information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of = use and=20 storage. Very hygroscopic.
Hazardous Decomposition = Products:=20
Acetone vapor (flammable, explosive) at temperatures above 160C = (320F),=20 also acrid fumes, possibly carbon monoxide.
Hazardous=20 Polymerization:
Will not occur.
Incompatibilities:=20
Strong oxidizers at high temperatures.
Conditions to = Avoid:=20
Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Investigated as a mutagen.

  =
--------\Cancer =
Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC =
Category
  ------------------------------------   -----    -----------    =
-------------
  Calcium Acetate (62-54-4)               No          No            None

12. Ecological Information

Environmental Fate:
No information found.=20
Environmental Toxicity:
No information found. =

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be = managed in an appropriate and approved waste disposal facility. = Processing,=20 use or contamination of this product may change the waste management = options.=20 State and local disposal regulations may differ from federal disposal=20 regulations. Dispose of container and unused contents in accordance = with=20 federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

  --------\Chemical Inventory Status - =
Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  =
Australia
  -----------------------------------------------  ----  ---  -----  =
---------
  Calcium Acetate (62-54-4)                         Yes  Yes   Yes      =
Yes                                     =20
=20
  --------\Chemical Inventory Status - Part =
2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  =
Phil.
  -----------------------------------------------  -----  ---   ----  =
-----
  Calcium Acetate (62-54-4)                         Yes   Yes   No     =
Yes     =20
=20
  --------\Federal, State & International Regulations - Part =
1\----------------
                                             -SARA 302-    ------SARA =
313------
  Ingredient                                 RQ    TPQ     List  =
Chemical Catg.
  -----------------------------------------  ---   -----   ----  =
--------------
  Calcium Acetate (62-54-4)                  No    No      No         No
=20
  --------\Federal, State & International Regulations - Part =
2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d)=20
  -----------------------------------------  ------     ------    ------
  Calcium Acetate (62-54-4)                  No         No         No    =

=20
=20
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: No       Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Pure / Solid)=20

Australian Hazchem Code: None allocated.=20
Poison Schedule: None allocated.
WHMIS:
This = MSDS=20 has been prepared according to the hazard criteria of the Controlled = Products=20 Regulations (CPR) and the MSDS contains all of the information = required by the=20 CPR.

16. Other Information

NFPA Ratings: Health: 0 Flammability: 0 = Reactivity: 0
Label Hazard Warning:
As part of = good=20 industrial and personal hygiene and safety procedure, avoid all = unnecessary=20 exposure to the chemical substance and ensure prompt removal from = skin, eyes=20 and clothing.
Label Precautions:
None.
Label = First=20 Aid:
Not applicable.
Product Use:
Laboratory = Reagent.=20
Revision Information:
MSDS Section(s) changed since = last=20 revision of document include: 8.
Disclaimer:=20 =
*********************************************************************= ***************************=20
Mallinckrodt Baker, Inc. provides the information contained = herein in=20 good faith but makes no representation as to its comprehensiveness or=20 accuracy. This document is intended only as a guide to the appropriate = precautionary handling of the material by a properly trained person = using this=20 product. Individuals receiving the information must exercise their = independent=20 judgment in determining its appropriateness for a particular purpose.=20 MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, = EITHER=20 EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF=20 MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE=20 INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION = REFERS.=20 ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR = DAMAGES=20 RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.=20 =
*********************************************************************= ***************************=20
Prepared by: Environmental Health & Safety
Phone = Number:=20 (314) 654-1600 (U.S.A.)

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