OCCUPATIONAL HEALTH SERVICES INC -- O-PHENYLENEDIAMINE DIHYDROCHLORIDE  -- 6840-00N060147
<pre>=====================  Product Identification  =====================

Product ID:O-PHENYLENEDIAMINE DIHYDROCHLORIDE
MSDS Date:06/30/1994
FSC:6840
NIIN:00N060147
=== Responsible Party ===
Company Name:OCCUPATIONAL HEALTH SERVICES INC
Address:11 WEST 42ND ST 12TH FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Info Phone Num:800-445-6737
Emergency Phone Num:615-366-2000
CAGE:DO501
=== Contractor Identification ===
Company Name:OCCUPATIONAL HEA & SAFETY,FORD MOTOR CO
Address:900 PARKLANE TOWERS WEST
City:DEARBORNE
State:MI
ZIP:48126
Phone:800-959-3673
CAGE:DO501
Company Name:OCCUPATIONAL HEALTH SERVICES INC
Address:11 W 42ND ST 12 THE FLOOR
City:NEW YORK
State:NY
ZIP:10036
Country:US
Phone:212-789-3535
CAGE:0G9K0

=============  Composition/Information on Ingredients  =============

Ingred Name:O-PHENYLENEDIAMINE DIHYDROCHLORIDE
CAS:615-28-1
RTECS #:ST0175000
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SUPDAT:KEEP UPWIND.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP:HEMORRHAGE OF LUNGS, NECROSIS & NEPHRITIS
    OF KIDNEYS, NECROSIS OF LIVER & METHEMOGLOBINEMIA W/(ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:CYANOSIS. SOME AROMATIC AMINES ARE STRONG SENSITS
    CAUSING SEV ALLERGIC RESPONSES. SKIN:MAY CAUSE (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:IRRIT TO SEV BURNS. WHEN APPLIED TO GUINEA PIGS IT
    CAUSES MOD IRRIT. SENSIT DERM MAY OCCUR TO PREVIOUSLY (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:EXPOSED PERSONS. EYE:MAY CAUSE IRRIT TO SEV BURNS.
    INGEST:SOME AROMATIC AMINES ARE STRONG (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:IRRITS & MAY BE ABSORBED THROUGH DIGEST TRACT CAUSING
    EFTS AS DETAILED IN ACUTE INHAL. CHRONIC:SKIN:RPTD (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:OR PRLNGD CONT MAY CAUSE SENSIT DERM.
    EYES:RPTD/PRLNGD CONT W/IRRITS MAY CAUSE CONJUNCT. INGEST:AS EVAL
    (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:BY RTECS, ADMIN TO MICE RSLTD IN
    STATISTICALLYSIGNIFICANT INCREASE IN INCIDENCE OF CARCIN TUMORS OF
    LIVER.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:UNTIL NO EVIDENCE OF CHEM REMAINS (@ LST 15
    MIN). GET MED ATTN IMMED. INGEST:IF VOMIT OCCURS, (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:KEEP HEAD LOWER/HIPS TO HELP PVNT ASPIR. TREAT
    SYMPTOMATICALLY & SUPPORTIVELY. NOTE TO MD:NO SPECIFIC (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:SPECIFIC OPERATION, MUST NOT EXCEED WORKING LIMS
    OF RESP & MUST BE JOINTLY APPRVD BY NATNL INSTITUTE (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:FOR OCCUP SFTY & HLTH & MINE SFTY & HLTH ADMIN
    (NIOSH/MSHA). ANY DUST & MIST RESP. ANY AIR-PURIFYING RESP(ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:W/HIGH-EFFICIENCY PARTICULATE FILTER. ANY POWERED
    AIR-PURIFYING RESP W/DUST & MIST FILTER. ANY POWERED (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:AIR-PURIFYING RESP W/HIGH-EFFICIENCY PARTICULATE
    FILTER. ANY TYPE 'C' SUPPLIED-AIR RESP OPERATED IN (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:PRESS-DEMAND/OTHER POSITIVE PRESS/CONTINUOUS-FLOW
    MODE. ANY SCBA. FOR FIREFIGHT & OTHER IMMED DANGEROUS (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:TO LIFE/HLTH CNDTNS:ANY SCBA THAT HAS FULL FACEPIECE
    & IS OPERATED IN PRESS-DEMAND/OTHER POSITIVE-PRESS (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:MODE. ANY SUPPLIED-AIR RESP THAT HAS FULL FACEPIECE
    & IS OPERATED IN PRESS-DEMAND/OTHER POS-PRESS MODE (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:IN COMBINATION W/AUXILIARY SCBA OPERATED IN
    PRESS-DEMAND/OTHER POS-PRESS MODE.
RTECS #:9999999ZZ

Ingred Name:EYE PROT:AND FULL LENGTH FACE SHIELD .
RTECS #:9999999ZZ

Ingred Name:OTHER PROT EQUIP:FOUNTAIN & DELUGE SHOWER W/IN IMMED WORK
    AREA FOR EMER USE. EMPLOYEE MUST WEAR APPROP PROT (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22:(IMPERVIOUS) CLTHG & EQUIP TO PVNT RPTD/PRLNGD SKIN
    CONT W/THIS SUBSTANCE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE BLUISH SKIN
    COLOR & KIDNEY DMG. SKIN:MAY CAUSE IRRIT. MAY CAUSE ALLERGIC RXNS.
    ADDNL EFTS MAY INCLUDE BURNS. EYES:MAY CAUSE IRRIT. ADDNL EFTS MAY
    INCLUDE BURNS. INGEST:NO INFORMA TION AVAIL ON SIGNIFICANT ADVERSE
    EFTS.CHRONIC:INHAL:NO INFORMATION AVAILABLE. SKIN:SAME AS ACUTE.
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:EYES:SAME AS ACUTE. INGEST:NO
    INFORMATION AVAILABLE ON SIGNIFICANT ADVERSE EFFECTS. TOX
    INFO:IRRITANT-SKIN, EYE. TARGET EFFECTS-SENSITIZER-DERMAL.
    POISONING MAY AFFECT THE LUNGS, LIVER, KIDN EYS AND BLOOD.
    INHALATION:ACUTE:AROMATIC AMINES MAY CAUSE EDEMA AND (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC.
    KEEP PERSON WARM AND AT REST. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
    GET MED ATTN. IMMED. SKIN:REMOVE CONTAM CLTHG & SHOES IMMED. WASH
    W/SOAP/ MILD DETERGENT & LG AMTS OF WATER UNTILNO EVIDENCE OF CHEM
    REMAINS (AT LST 15-20 MIN). GET MED ATTN IMMED. EYES:WASH IMMED
    W/LG AMTS OF WATER/NORMAL SALINE, OCCAS LIFTING UPPER & LOWER LIDS,
    (SUPDAT)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:(1993 EMER RESPONSE GUIDEBOOK, RSPA P 5800.6). DRY
    CHEM, CARBON DIOXIDE, WATER SPRAY/REG FOAM. LARGER FIRES:(SUPP
    DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
    MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. DO NOT
    SCATTER SPILLED MATL W/HIGH-PRESS (SUPP DATA)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSURE TO HEAT
    OR FLAME DUST-AIR MIXTURE MAY IGNITE OR EXPLODE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY
    CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED
    MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
    STORING SUBSTANCE. STORE & HNDL UNDER ARGON. STORE AT ROOM
    TEMPERATURE. STORE IN A COOL, DRY PLACE.
Other Precautions:KEEP CNTNR TIGHTLY CLSD. PROT FROM EXPOS TO
    AIR/LIGHT. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. PREVENT EYE
    CONTACT. PREVENT REPEATED OR PROLONGED SKIN CONTACT.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:FOLLOWING RESPS ARE REC BASED ON INFO FOUND IN
    PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER
    FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON
    CONTAM LEVELS FOUND  IN WORK PLACE, MUST BE BASED ON (ING 13)
Ventilation:PROVIDE LOC EXHST VENT. VENT EQUIP SHOULD BE EXPLO-PROOF IF
    EXPLO CONCS OF DUST, VAP/FUME ARE PRESENT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 21)
Other Protective Equipment:WHERE THERE IS ANY POSS THAT AN EMPLOYEE'S
    EYES MAY BE EXPOSED TO SUBSTANCE, EMPLOYER SHOULD PROVIDE AN EYE
    WASH(ING 23)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MP:>495F,>257C(DECOMPOSES). APPEAR & ODOR:SOLID/NEEDLES W/AN IRRIT
    ODOR. EXTING MEDIA:WATER SPRAY, FOG/REG FOAM. FIRE FIGHT PROC:WATER
    STREAMS. DIKE FIRE-CTL WATER FOR LATER DISP (1993 EMER RESPONSE G
    UIDEBOOK, RSPA P 5800.6, GUIDE PG 31). USE AGENTS SUITABLE FOR TYPE
    OF SURROUNDING FIRE. AVOID BRTHG HAZ VAPS, (ING 2)

==================  Physical/Chemical Properties  ==================

Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Vapor Pres:0 @ 20C
Spec Gravity:1.0
Evaporation Rate &amp; Reference:0 (BUTYL ACETATE=1)
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS, CLEAR, WHITE TO TAN TO SLIGHTLY
    REDDISH/VIOLET CRYSTALLINE (SUP DAT)
Percent Volatiles by Volume:0

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
O-PHENYLENEDIAMINE DIHYDROCHLORIDE:OXIDZERS (STRONG):FIRE AND EXPLOSION
    HAZARD.
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY.
    AVOID CONTACT WITH STRONG OXIDIZERS, EXCESSIVE HEAT, SPARKS OR OPEN
    FLAMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
    INCLUDE TOXIC AND CORROSIVE FUMES OF HYDROGEN CHLORIDE & OXIDES OF
    CARBON & NITROGEN.

====================  Disposal Considerations  ====================

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
    WHEN DISPOSING OF THIS SUBSTANCE.

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 of Defense.  The United States of America in no manner whatsoever,
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 disclaims all liability for its use.  Any person utilizing this
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